O. A. Tomashenko, V. V. Grushin "Aromatic Trifluoromethylation with Metal Complexes"
Chem. Rev.
2011,
111, 4475.
[Cited ≥ 1,578 times according to Google Scholar];
Highlighted in: Chemical & Engineering News 2012, February 27, 10.Y. Wang, N. Herron, V. V. Grushin, D. LeCloux, V. Petrov "Highly Efficient Electroluminescent Materials Based on Fluorinated Organometallic Iridium Compounds"
Appl. Phys. Lett. 2001,
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[Cited ≥ 912 times according to Google Scholar]V. V. Grushin "The Organometallic Fluorine Chemistry of Palladium and Rhodium: Studies toward Aromatic Fluorination"
Acc. Chem. Res. 2010,
43, 160.
[Cited ≥ 516 times according to Google Scholar];
Highlighted in: Organic Process Research & Development 2011, 15, 25.V. V. Grushin, N. Herron, D. D. Lecloux, W. J. Marshall, V. A. Petrov, Y. Wang "New, Efficient Electroluminescent Materials Based on Organometallic Ir Complexes"
Chem. Commun.,
2001, 1494.
[Cited ≥ 382 times according to Google Scholar];
Highlighted in: Chemical & Engineering News 2001, August 27, 17.V. Grushin, D. D. LeCloux, V. A. Petrov, Y. Wang "Electroluminescent Iridium Compounds with Fluorinated Phenylpyridines, Phenylpyrimidines, and Phenylquinolines and Devices Made with Such Compounds"
U.S. Patent 2003, US 6,670,645.
[Cited ≥ 357 times according to Google Scholar]A. Zanardi, M. A. Novikov, E. Martin, J. Benet-Buchholz, V. V. Grushin "Direct Cupration of Fluoroform"
J. Am. Chem. Soc. 2011,
133, 20901.
[Cited ≥ 336 times according to Google Scholar];
Number 1 most read JACS paper (Dec 2011 – Feb 2012). Highlighted in: (a) Angew. Chem., Int. Ed. 2012, 51, 5048; (b) Nachrichten aus der Chemie 2013, 61, 265.V. V. Grushin, W. J. Marshall "Facile Ar-CF
3 Bond Formation at Pd. Strikingly Different Outcomes of Reductive Elimination from [(Ph
3P)
2Pd(CF
3)Ph] and [(Xantphos)Pd(CF
3)Ph]"
J. Am. Chem. Soc.
2006,
128, 12644.
[Cited ≥ 330 times according to Google Scholar];
Highlighted in: Kagaku (Chemistry; Japan) 2007, 62, 62.O. A. Tomashenko, E. C. Escudero-Adan, M. Martinez Belmonte, V. V. Grushin "Simple, Stable, and Easily Accessible Well-Defined CuCF
3 Aromatic Trifluoromethylating Agents"
Angew. Chem. Int. Ed. 2011,
50, 7655.
[Cited ≥ 268 times according to Google Scholar];
Highlighted in: Synfacts 2011, 11, 1236.V. V. Grushin "Palladium Fluoride Complexes: One More Step toward Metal-Mediated C-F Bond Formation"
[Cited ≥ 244 times according to Google Scholar];
Chem. Eur. J. 2002,
8, 1006.
Invited Contribution.V. V. Grushin "Thermal Stability, Decomposition Paths, and Ph/Ph Exchange Reactions of [(Ph
3P)
2Pd(Ph)X] (X = I, Br, Cl, F, and HF
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Organometallics 2000,
19, 1888.
[Cited ≥ 223 times according to Google Scholar]P. Novák, A. Lishchynskyi, V. V. Grushin "Fluoroform-Derived CuCF
3 for Low-Cost, Simple, Efficient, and Safe Trifluoromethylation of Arylboronic Acids in Air"
Angew. Chem., Int. Ed. 2012,
51, 7767.
[Cited ≥ 222 times according to Google Scholar]; Highlighted in: (a) Chemistry Views http://www.chemistryviews.org/details/ezine/2360471/Low-Cost_Simple_Efficient_Safe_Trifluoromethylation.html; (b) as a SynStory in Synform 2012, 11, A109; (c) Synfacts 2012, 8, 1246; (d) Organic Process Research & Development 2012, 16, 1464.A. Lishchynskyi, M. A. Novikov, E. Martin, E. C. Escudero-Adán, P. Novák, V. V. Grushin "Trifluoromethylation of Aryl and Heteroaryl Halides with Fluoroform-Derived CuCF
3: Scope, Limitations, and Mechanistic Features"
J. Org. Chem. 2013,
78, 11126.
[Cited ≥ 177 times according to Google Scholar];
Featured Article; JOC Cover; Top 3 most read J. Org. Chem. papers (Aug.-Oct. 2013); Top 10 most read J. Org. Chem. papers for over 1 year. Highlighted in: Organic Process Research & Development 2014, 18, 2.P. Novák, A. Lishchynskyi, V. V. Grushin "Trifluoromethylation of α-Halkoetones"
J. Am. Chem. Soc. 2012,
134, 16167.
[Cited ≥ 177 times according to Google Scholar];
Number 1 most read JACS paper (Oct.-Nov. 2012). Highlighted in: (a) Chemical & Engineering News 2012, October 1, 52; (b) Synfacts 2012, 8, 1366; (c) Organic Process Research & Development 2013, 17, 5; (d) Nachrichten aus der Chemie 2013, 61, 265.V. V. Grushin, W. J. Marshall "Unexpected H
2O-Induced Ar-X Activation with Trifluoromethylpalladium(II) Aryls"
J. Am. Chem. Soc.
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128, 4632.
[Cited ≥ 168 times according to Google Scholar]S. A. Macgregor, D. C. Roe, W. J. Marshall, K. M. Bloch, V. I. Bakhmutov, V. V. Grushin "The F/Ph Rearrangement Reaction of [(Ph
3P)
3RhF], the Fluoride Congener of Wilkinson’s Catalyst"
J. Am. Chem. Soc. 2005,
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[Cited ≥ 151 times according to Google Scholar]S. L. Fraser, M. Yu. Antipin, V. N. Khroustalyov, V. V. Grushin "Molecular Fluoro Palladium Complexes"
J. Am. Chem. Soc. 1997,
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[Cited ≥ 143 times according to Google Scholar]V. V. Grushin, W. J. Marshall "The Fluoro Analogue of Wilkinson's Catalyst and Unexpected Ph-Cl Activation"
J. Am. Chem. Soc. 2004,
126, 3068.
[Cited ≥ 128 times according to Google Scholar];
Highlighted in: Chemical & Engineering News 2004, March 22, 34.R. J. Young, Jr., V. V. Grushin "Catalytic C-F Bond Activation of Nonactivated Monofluoroarenes"
Organometallics 1999,
18, 294.
[Cited ≥ 122 times according to Google Scholar]M. C. Pilon, V. V. Grushin "Synthesis and Characterization of Organopalladium Complexes Containing a Fluoro Ligand"
Organometallics 1998,
17, 1774.
[Cited ≥ 115 times according to Google Scholar]J. P. Flemming, M. C. Pilon, O. Ya. Borbulevitch, M. Yu. Antipin, V. V. Grushin "The Trans-Influence of F, Cl, Br and I Ligands in a Series of Square-Planar Pd (II) Complexes. Relative Affinities of Halide Anions for the Metal Center in [(Ph
3P)
2Pd(Ph)]
+"
Inorg. Chim. Acta 1998,
280, 87.
[Cited ≥ 113 times according to Google Scholar];
Invited Contribution.V. V. Grushin, W. J. Marshall "Ar-F Reductive Elimination from Palladium(II) Revisited"
Organometallics 2007,
26, 4997.
[Cited ≥ 106 times according to Google Scholar]A. Lishchynskyi, V. V. Grushin "Cupration of C
2F
5H: Isolation, Structure, and Synthetic Applications of [K(DMF)
2][(
t-BuO)Cu(C
2F
5)]. Highly Efficient Pentafluoroethylation of Unactivated Aryl Bromides"
J. Am. Chem. Soc. 2013,
135, 12584.
[Cited ≥ 102 times according to Google Scholar]A. M. Romine, N. Nebra, A. I. Konovalov, E. Martin, J. Benet-Buchholz, V. V. Grushin "Easy Access to the Cu
III Anion [Cu(CF
3)
4]
-"
Angew. Chem., Int. Ed. 2015,
54, 2745.
[Cited ≥ 100 times according to Google Scholar]V. I. Bakhmutov, F. Bozoglian, K. Gómez, G. González, V. V. Grushin, S. A. Macgregor, E. Martin, F. M. Miloserdov, M. A. Novikov, J. A. Panetier, L. V. Romashov "CF
3-Ph Reductive Elimination from [(Xantphos)Pd(CF
3)(Ph)]"
Organometallics 2012,
31, 1315.
[Cited ≥ 93 times according to Google Scholar] (
Special Issue of Organometallics “Organometallic Chemistry Meets Fluorine”).
Invited Contribution.
V. V. Grushin, W. J. Marshall "Fluorination of Nonactivated Haloarenes via Arynes under "Mild Conditions, Resulting from Further Studies toward Ar-F Reductive Elimination from Pd(II)"
Organometallics 2008,
27, 4825.
[Cited ≥ 89 times according to Google Scholar]A. Lishchynskyi, G. Berthon, V. V. Grushin "Trifluoromethylation of Arenediazonium Salts with Fluoroform-Derived CuCF
3 in Aqueous Media"
Chem. Commun. 2014,
50, 10237.
[Cited ≥ 86 times according to Google Scholar];
Top 10 most read ChemComm papers (Jul. 2014).A. I. Konovalov, A. Lishchynskyi, V. V. Grushin "Mechanism of Trifluoromethylation of Aryl Halides with CuCF
3 and the Ortho-Effect"
J. Am. Chem. Soc. 2014,
136, 13410.
[Cited ≥ 73 times according to Google Scholar]D. C. Roe, W. J. Marshall, F. Davidson, P. D. Soper, V. V. Grushin "Structure and Solution Dynamics of [(Ph
3P)
2Pd(Ph)(FHF)]"
Organometallics 2000,
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[Cited ≥ 69 times according to Google Scholar]V. V. Grushin, W. J. Marshall "Is Fluoride Bonded to Two Pd Acceptors Still Basic? Three CH
2Cl
2 Molecules Encapsulating a Pd
2(m-F)
2 Square and New Implications for Catalysis"
Angew. Chem. 2002,
114, 4656;
Angew. Chem. Int. Ed. Engl. 2002,
41, 4476.
[Cited ≥ 65 times according to Google Scholar]V. V. Grushin "Generation of “Naked” Fluoride Ions in Unprecedentedly High Concentrations from a Fluoropalladium Complex"
Angew. Chem. 1998,
110, 1042.
Angew. Chem. Int. Ed. Engl. 1998,
37, 994.
[Cited ≥ 64 times according to Google Scholar];
Highlighted in: Nachrichten aus Chemie Technik und Laboratorium 1998, 46, 410.V. V. Grushin, W. J. Marshall "Trans-Difluoro Complexes of Pd(II)"
J. Am. Chem. Soc. 2009,
131, 918.
[Cited ≥ 61 times according to Google Scholar]A. I. Konovalov, J. Benet-Buchholz, E. Martin, V. V. Grushin "The Striking Critical Effect of the Countercation in the Direct Cupration of Fluoroform with [Cu(OR)
2]
-"
Angew. Chem., Int. Ed. 2013,
52, 11637.
[Cited ≥ 60 times according to Google Scholar]N. Nebra, V. V. Grushin "Distinct Mechanism of Oxidative Trifluoromethylation with a Well-Defined Cu(II) Fluoride: Hidden Catalysis"
J. Am. Chem. Soc. 2014,
136, 16998.
[Cited ≥ 59 times according to Google Scholar]J. Goodman, V. V. Grushin, R. B. Larichev, S. A. Macgregor, W. J. Marshall, D. C. Roe "Fluxionality of [(Ph
3P)
3M(X)] (M = Rh, Ir). The Red and Orange Forms of [(Ph
3P)
3Ir(Cl)]. Which Phosphine Dissociates Faster from Wilkinson's Catalyst?"
J. Am. Chem. Soc. 2010,
132, 12013.
[Cited ≥ 58 times according to Google Scholar]J. Goodman, V. V. Grushin, R. B. Larichev, S. A. Macgregor, W. J. Marshall, D. C. Roe "Fluxionality of [(Ph3P)
3Rh(X)]: the Extreme Case of X = CF
3"
J. Am. Chem. Soc. 2009,
131, 4236.
[Cited ≥ 58 times according to Google Scholar]A. Garcia-Algarra, V. V. Grushin, S. A. Macgregor "A Natural Bond Orbital Analysis of the Electronic Structure of [L
nM-CH
3] and [L
nM-CF
3] Complexes"
Organometallics 2012,
31, 1467.
[Cited ≥ 56 times according to Google Scholar]; (
Special Issue of Organometallics “Organometallic Chemistry Meets Fluorine”).
Invited Contribution.
J. Jover, F. M. Miloserdov, J. Benet-Buchholz, V. V. Grushin, F. Maseras "On the Feasibility of Ni-catalyzed Trifluoromethylation of Aryl Halides"
Organometallics 2014,
33, 6531.
[Cited ≥ 46 times according to Google Scholar];
Top 20 most read Organometallics papers (Nov. 2014- Nov. 2015).Z. Mazloomi, A. Bansode, P. Benavente, A. Lishchynskyi, A. Urakawa, V. V. Grushin "Continuous Process for Production of CuCF
3 via Direct Cupration of Fluoroform"
Org. Process Res. Dev. 2014,
18, 1020.
[Cited ≥ 44 times according to Google Scholar]; (
Special Issue of OPRD “Fluorine Chemistry”).
Invited Contribution.
Top 10 most read OPRD papers (June-Jul. 2014).V. V. Grushin "Fluoroform as a Feedstock for High-Value Fluorochemicals: Novel Trends and Recent Developments"
Chim. Oggi – Chem. Today 2014,
32, 81.
[Cited ≥ 41 times according to Google Scholar]Invited Contribution.
W. J. Marshall, D. L. Thorn, V. V. Grushin "Single Crystal X-ray and Solution
13C NMR Study of Fluoro(p-nitrophenyl)bis(triphenylphosphine)palladium(II). Are There Effects of Through-Conjugation?"
Organometallics 1998,
17, 5427.
[Cited ≥ 41 times according to Google Scholar]W. J. Marshall, V. V. Grushin "Unexpected Outcome of the Reaction of [(COD)
2Rh
2(m-OH)
2] with TREAT HF or 50% HF. Peculiar Structural Features and Diminished Fluoride Basicity of [(R
3P)
4Rh
2(m-F)
2] (R = i-Pr, Ph)"
Organometallics 2004,
23, 3343.
[Cited ≥ 40 times according to Google Scholar]L. I. Panferova, F. M. Miloserdov, A. Lishchynskyi, M. Martínez Belmonte, J. Benet-Buchholz, V. V. Grushin "Well-Defined CuC
2F
5 Complexes and Pentafluoroethylation of Acid Chlorides"
Angew. Chem., Int. Ed. 2015,
54, 5218.
[Cited ≥ 40 times according to Google Scholar];
VIP Paper.A. I. Konovalov, E. O. Gorbacheva, F. M. Miloserdov, V. V. Grushin "Ruthenium-Catalyzed Nucleophilic Fluorination of Halobenzenes"
Chem. Commun. 2015,
51, 13527.
[Cited ≥ 40 times according to Google Scholar]A. Lishchynskyi, Z. Mazloomi, V. V. Grushin "Trifluoromethylation and Pentafluoroethylation of Vinylic Halides with Low-Cost R
fH-Derived CuR
f (R
f = CF
3, C
2F
5)"
Synlett 2015,
26, 45.
[Cited ≥ 38 times according to Google Scholar]; (
Cluster Issue).
Invited Contribution.
S. Takemoto, V. V. Grushin "Nucleophile-Catalyzed, Facile, and Highly Selective C−H Activation of Fluoroform with Pd(II)"
J. Am. Chem. Soc. 2013,
135, 16837.
[Cited ≥ 32 times according to Google Scholar];
Highlighted in: Chemical & Engineering News 2013, November 11, 27.V. Grushin "Process for preparing fluoroarenes from haloarenes"
U.S. Patent 2007, US 7,202,388.
[Cited ≥ 25 times according to Google Scholar]V. A. Petrov, W. J. Marshall, V. V. Grushin "The First Perfluoroacetylacetonate Metal Complexes: As Unexpectedly Robust as Tricky to Make"
Chem. Commun. 2002, 520.
[Cited ≥ 23 times according to Google Scholar]W. J. Marshall, G. Aullón, S. Alvarez, K. D. Dobbs, V. V. Grushin "”To Bend or Not to Bend?” Both! The Planar and Bent Structures of [(Ph
3P)
4Rh
2(m-F)
2]"
Eur. J. Inorg. Chem. 2006, 3340.
[Cited ≥ 5 times according to Google Scholar]V. Grushin, A. Zanardi "Process to obtain a trifluoromethylating composition"
U.S. Patent 2017, US 9,676,795;
European Patent 2016, EP 2678302.
V. Grushin, A. Lishchynskyi "Pentafluoroethylating compositions"
PCT 2015, WO 2015018855 A1.
A. Lishchynskyi, P. Novák, V. V. Grushin "Trifluoromethylation" In:
Science of Synthesis: C-1 Building Blocks in Organic Synthesis 2, P. W. N. M. van Leeuwen, Ed., Thieme,
2013, p 367-408.
Invited Contribution.
V. Grushin "Perfluoroalkylated benzoate surfactants"
U.S. Patent 2011, US 7,968,608.
